The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Acylperoxy / CH3C(O)O2 / Moortgat(1989)_298K_195-280nm(resc,L-rev)

DATAFILE: CH3C(O)O2_Moortgat(1989)_298K_195-280nm(resc,L-rev).txt
NAME: acetylperoxy radical
FORMULA: CH3C(O)O2
AUTHOR(YEAR): Moortgat(1989)
T: 298K
λ: 195-280nm(resc,L-rev)
BIBLIOGRAPHY: G.K. Moortgat, B. Veyret, and R. Lesclaux, "Absorption spectrum and kinetics of reactions of the acetylperoxy radical", J. Phys. Chem. 93, 2362-2368 (1989); DOI: 10.1021/j100343a032
COMMENTS: L-rev = Lightfoot review

The absorption cross sections were rescaled by

P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry," Atmos. Environ. 26A, 1805-1961 (1992); DOI: 10.1016/0960-1686(92)90423-I,

to the value σ(210nm) = 4.17×10-18 cm2 molecule-1 recommended for HO2

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